EPA: Hazard Summary - Toluene. 128. May cause central nervous system depression. Toluene Synonyms & Trade Names Methyl benzene, Methyl benzol, Phenyl methane, Toluol CAS No. Aggravation of Pre-existing Conditions: Persons with pre-existing skin disorders or impaired liver or kidney function may be more susceptible to the effects of this substance. Hazard symbol(s) and hazard statement (s) Toluene > 99.0 108-88-3 203-625-9 Flam. Inhalation of vapor may cause respiratory tract irritation. More Info. CAMEO Chemicals Colorless liquid with a sweet odor; [NIOSH] Benzene is common in unleaded fuel, where it is added as a substitute for lead, allowing smoother running. Precautionary statements P280-P305 + P351 + P338. The 'Substance identity' section is calculated from substance identification information from all ECHA databases. Decomposes with emission of toxic oxides of nitrogen at high temperatures. U220; A toxic waste when a discarded commercial chemical product or manufacturing chemical intermediate or an off-specification commercial chemical product or manufacturing chemical intermediate. May cause genetic defects. Tested to withstand exposure to Acetone, Dichloromethane, Hydrofluoric Acid, and other tough chemicals and solvents. Digitally printed for vivid colors on designs or logos. Chemsrc provides Toluene-d8(CAS#:2037-26-5) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Find more information on this substance at: PubChem . Toluene Diisocyanate Revision Date: 06-June-2017 Version 1.1 1. H319 Causes serious eye irritation. Available in various quantities and reagent grades, it is used as a precursor to benzene, a solvent, an octane booster in gasoline, etc. 2,4-Toluene diisocyanate . May cause damage to the central nervous system by inhalation. P260 Do not breathe dust/fume/gas/mist/vapours/spray. TOLUENE Description OSHA DANGER TOLUENE Sign or Label with Symbol and Text This OSHA-format Chemical sign with bold text and GHS symbol makes your Hazmat message clear to employees, visitors and inspectors. Hazard statements GHS Classification. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 03/21/2014 Revision date: 02/27/2018 Supersedes: 03/21/2014 Version: 1.1 . Material options might include pipe markers, roll labels and stencils in addition to aluminum, plastic, magnetic backing and paper or vinyl labels. 2. Benzene, Toluene, Xylene (BTX) / Hydrogenated Pygas (HPG) Version 4.2 Revision Date 2021-09-22 SDS Number:100000067417 1/22 SECTION 1: Identification of the substance/mixture and of the company/undertaking . Hence floats on water. DOT Symbols : + - Fixes (cannot be altered) proper shipping name, hazard class, and packing group Toluene is typically used in a mixture with other solvents and chemicals such as paint pigments. Used in aviation and automotive fuels, as a solvent, and to make other chemicals. H304: May be fatal if swallowed . Vapors may cause dizziness or suffocation. . Aspiration hazard, Category 1 Acute aquatic toxicity, Category 2 Hazard Symbol : Signal Word : Danger Hazard Statements : H225 : Flammable liquid and vapor. 108-88-3 Toluene >99 203-625-9 Hazard Symbols: XN F Risk Phrases: 11 20 Section 3 - Hazards Identification Emergency Overview Appearance: Colorless. EC No. Flash point 20F. Shipping Name Toluene Toluene Hazard Class 3 3 (9.2) UN Number UN1294 UN1294 Packing Group II II Section 15 - Regulatory Information Dependable 3M adhesive vinyl that is built to resist harsh conditions. TDI Pure Suppliers. Hazards Toluene was first isolated as aromatic extract from the tropical Colombian tree Myroxylon balsamum. 2 mils thick adhesive sticks to all surfaces (even carpets). Vinyl toluene (25013-15-4) is also called Vinyltoluene isomers mixture,inhibited; 3,4-vinyltoluene (mixedisomers); alpha,beta-styrene; ar-ethenylmethylbenzene; ar-methyl-styren; ethenylmethyl-benzen; methylethenylbenzene; allyl benzene.It is colorless liquid with a strong, disagreeable odor. EPA Hazardous Waste No. Health Hazards . 2; H225 Asp. Vapors may form explosive mixtures with air. Two of the six possible isomers are commercially important: 2,4-TDI (CAS: 584-84-9) and 2,6-TDI (CAS: 91-08-7). Signal: Danger. : 601-021-00-3 CAS-No. No smoking. WARNING: This product contains Toluene, a chemical known to the state of California to cause developmental reproductive toxicity. Severe eye irritant. Study with Quizlet and memorize flashcards containing terms like Explosives (Hazard Class 1) Division 1.1: Mass Explosion Hazard Examples: Black powder, dynamite, T-N-T, Explosives (Hazard Class 1) Division 1.2: Projection Hazard Examples: Aerial Flares, detonation cord, and power device cartridges., Explosives (Hazard Class 1) Division 1.3: Fire Hazard Examples: Liquid-fueled rocket motors . Emergency Response Guide No. It has a stimulating effect on the skin and mucosa, and has a narcotic effect on the central nervous system. Flammable liquid and vapor. aspiration hazard. Toluene vapor has a sharp or sweet odor, which is a sign of exposure. Irritates skin and eyes. Symbol: GHS02, GHS07, GHS08 Signal Word: Danger UN No. The chemical formula of toluene can be written as C6H5CH3. May be absorbed through intact skin. 2 mil thick white polyester with matte finish. Machine washable for fabrics. GHS Toluene Labels (79654) Toluene: Highly flammable liquid and vapor. May cause sensitization by skin contact. Slightly soluble in water and neutrally buoyant in water. More Information. (See Section 4.1.5 and Figure 9.1(a) of NFPA 704) The six o'clock position on the symbol represents special hazards and has a white background. Toluene (CAS 108-88-3) GHS Chemical Container Label. Vinyl toluene is used to synthesize organic compound. Chemical name Toluene-2,4-di-isocyanate (4-methyl-m-phenylene diisocyanate) Hazard Statements H330 Fatal if inhaled. . Toluene - Safety rat oral LD50:7.53g/kg. Protection from direct sunlight. European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN F Vapors heavier than air. NFPA Hazard ID: Health: 2 Flammability: 3 Reactivity: 0 HMIS Hazard ID: Health: 2* Flammability: 3 Reactivity: 0 . Most important symptoms and effects, both acute and delayed: Irritation.Shortness of breath.Headache.Nausea.Dizziness.The substance is irritating to the eyes and respiratory tract. Distant ignition and flashback are possible. SECTION 2: Hazards identification 2.1 Classification of the substance or mixture GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) Special Remarks on Fire Hazards: Flaming occurs when liquid chlorine in n-Heptane is added to added to red phosphorous. Insoluble in water and less dense than water. Special Remarks on Explosion Hazards: Vapors may form explosive mixtures in air. Find here p-Toluene sulphonyl chloride, 98% manufacturers, suppliers & exporters in India with worldwide shipping. It is insoluble in water, but miscible with benzene, alcohol, ether and other organic solvents. Toluene V4054a-TOLUENE- Toluene TOLUENE TOL 108-88-3 203-625-9 . Flammability: 3 (Serious) H336 : May cause drowsiness or dizziness. Safety Information Hazard Symbols Symbol GHS02GHS07GHS08 GHS02, GHS07, GHS08 2; H315 STOT SE 3; H336 Repr. Application Toluene undergoes alkylation in the presence of modified ZSM (Zeolite Socony Mobil)-5-class zeolite catalysts to form p-xylene with high selectivity. 4-cyano-toluene - Names and Identifiers. H315 Causes skin irritation. May cause drowsiness or dizziness. GHS Hazard Statements. Toluene is a naturally occurring compound derived primarily from petroleum or petrochemical processes. Aspiration hazard, Category 1 Labeling Symbol(s) : Signal Word: Danger Hazard Statements : H225: Highly flammable liquid and vapor. It was designed on the base of the table from the Wikimedia Commons article "GHS hazard symbols". 2,4-Toluene diisocyanate is primarily used as a chemical intermediate in the production of polyurenthane products. What are the most important things to know about toluene in an emergency? Rinse SKIN with water/shower. Articles of Toluene-d8 are included as well. literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. Hazard(s) identification Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Label Elements Signal Word Company Fisher Scientific Company One Reagent Lane Fair Lawn, NJ 07410 Tel: (201) 796-7100 Acros Organics One Reagent Lane Fair Lawn, NJ 07410 Skin Corrosion/Irritation . What is Toluene 3. XS5250000 DOT ID & Guide 1294 130 Formula CHCH Conversion 1 ppm = 3.77 mg/m 3 IDLH 500 ppm See: 108883 Exposure Limits NIOSH REL TWA 100 ppm (375 mg/m 3) ST 150 ppm (560 mg/m 3 ) OSHA PEL H225: Highly Flammable liquid and vapor [ Danger Flammable liquids] H304: May be fatal if swallowed and enters airways [ Danger Aspiration hazard] H315: Causes skin irritation [ Warning Skin corrosion/irritation] H336: May cause drowsiness or dizziness [ Warning Specific target organ . Tox. 2 - HAZARDS IDENTIFICATION GHS HAZARD CLASSIFICATION: Physical Hazards . (In the example, "toluene" is a PSN.) 67/548/EC . Used in making dyes. A clear colorless liquid with a characteristic aromatic odor. F005; A hazardous waste from nonspecific sources when a spent solvent. 108-88-3 RTECS No. : 1294 IMCO Class No. "Hazard symbols or warning symbols are recognisable symbols designed to warn about hazardous materials, locations, or objects, including electric currents, poisons, and radioactivity. Exposure to toluene may affect the developing fetus. Toluene is a common component in gasoline, glues, and paint products. If this liquid is swallowed, aspiration into the lungs may result in chemical pneumonitis. The hazard identification signal is a color-coded array of four numbers or letters arranged in a diamond shape. These cement are mostly used to seal joints in concrete, wood, metal, or masonry buildings. * Exposure to hazardous substances should be routinely evaluated. Page 6 of 16 MSDS - Toluene . 584-84-9 . Generally, commercial material comes as a mixture of the two isomers. may be harmful if swallowed. H304 : May be fatal if swallowed and enters airways. Product name : Toluene Product Number : 244511 Brand : Sigma-Aldrich Index-No. Exposure to toluene may occur from breathing ambient or indoor air affected by such sources. Aspiration hazard if swallowed; can enter lungs and cause damage. Can float on water and spread fire. Flammable liquids are: A liquid having a flash point of = 60.5 C (141 F) Any material in a liquid phase with a flash point = 37.8 C (100 F) that is intentionally heated and offered for transport or transported at or above its flash point in bulk packaging. TOLUENE Hazard Class: 3.2 UN/NA . Toluene is an organic, water-insoluble, liquid aromatic hydrocarbon consisting of a CH3 group attached to a phenyl group. Aromatic odour. Signal word Danger. Toluene, sec-Butyl Acetate, Benzene and Isobutyl Alcohol all have/are known interferences. Reactivity Alerts none Air & Water Reactions Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type . vapor may cause flash fire. Toluene Signs and Labels Here you'll find safety signs, labels and pipe markers, as well as NFPA diamonds, GHS labels, PPE and other warnings for Toluene. : 3 Packing Group: II Hazardous Statement: H225-H304-H315-H336-H361d-H373 Precaution Statement: P210-P261-P281-P301 + P310-P331. 2,4-TDI is produced in the pure state. Causes skin irritation. How do you categorize the type of hazards in laboratory? Long-term effect can affect the liver and kidney function. H351 Suspected of causing cancer. Additional symbols are commonly included. Store in a cool, ventilated warehouse. The central nervous system (CNS) is the primary target organ for toluene toxicity in both humans and animals for acute (short-term) and chronic (long-term . The IUPAC name for toluene is methylbenzene. Toluene mixes readily with many organic solvents, but is poorly soluble in water. Hazard statements (GHS-US) : H225 - Highly flammable liquid and vapour. Benzene is found in ambient air as a result of burning fuels, such as coal, petrol and wood. H315 : Causes skin irritation. Symbol (GHS) Signal word Danger Precautionary statements P210 Keep away from heat/sparks/open flames/hot surfaces. Less dense than water (7.2 lb / gal) and insoluble in water. H317 May cause an allergic skin reaction. By referring from the hazard symbols in laboratory. 108-88-3 Toluene 100 Section 3 - Hazards Identification Emergency Overview Appearance: Clear, colorless solution Warning! 2,4-Toluene diisocyanate is extremely toxic from acute (short-term) and chronic (long-term) exposures. Use indoors or outdoors. Examples of some D-1 materials include carbon monoxide, sodium cyanide, sulphuric acid, toluene-2,4-diisocyanate (TDI), and acrylonitrile. Benzene (C 6 H 6) is a clear, colourless and flammable liquid with a sweet petrol-like smell. INGREDIENTS Components CAS Number Concentration (Weight) Toluenediisocyanate, 2,6 91-08-7 20 + 1 Toluenediisocyanate, 2,4 584-84-9 80 + 1 CHEMICAL FAMILY: Isocyanates 3. This may include collecting personal and area air samples. Workers may be harmed from exposure to toluene. Column 3: Hazard Class or Division . The federal OSHA Hazard Communication Standard, 1910.1200, requires private employers to provide similar training and information to their employees. Toluene is a clear, colorless liquid which becomes a vapor when exposed to air at room temperature. Keep the container sealed. Toluene 50 - 70 108-88-3 Acetone 20 - 30 67-64-1 Isopropyl alcohol 5 - 10 67-63- Petroleum Ether 15 - 25 8032-32-4 Toluene diisocyanate (TDI) is an organic compound with the formula CH3C6H3 (NCO)2. Flash Point: 40F. Environ Health Perspect 94: 237-244, 1991. . It is a colorless, water-insoluble liquid with the smell associated with paint thinners. Hazard class table. Toluene. Symbols: Hazardous materials descriptions and proper shipping names: Hazard Class or Division: Identification Numbers: PG: Label Codes: Special provisions (172.102) Packaging: Quantity limitations: Vessel stowage: . Extract from the Wikimedia Commons article & quot ; GHS hazard symbols: - Substance identity & # x27 ; section is calculated from substance identification information all. For Class D - Division 1 ( D-1 ) is an toluene hazard symbol hydrocarbon this compound is about 92.14.. 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